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CZTSSe thin film solar cell is a new type of high-efficiency thin film solar cell. It has become a hot spot in the photovoltaic field because of its high absorptivity (∼104 cm−1), high weak light response, high stability, potentially low cost, and environment friendliness [1], [2]. As an optical absorber layer, CZTSSe is an intrinsic P-type multicomponent compound semiconductor material.
Among the methods applied to modify the characteristics of CdSeTe/CdTe stacks, one of the most well-known and widely used procedures is the CdCl2 halide treatment. In this connection, the influence of CdCl2 on microstructural properties, phase distribution and optical properties of CdSeTe/CdTe stack depending on location of the employed surface was investigated.
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