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Mathematics > Symplectic Geometry
In this paper, we study obstructions to smoothing nodal orbicurves with orbighosts mapped into cyclic quotient singularities.
Catalytic asymmetric sulfonimidoyl transfer to access chiral sulfonimidoyl fluorides and related derivatives - Nature Chemistry
Abstract Sulfur fluoride exchange (SuFEx) click chemistry is a powerful tool for constructing functional molecules. However, catalytic asymmetric methods for constructing chiral sulfur(VI)-centred sulfonimidoyl fluorides are rare, resulting in the limited application of SuFEx. Owing to the crowded three-dimensional environment, chiral sulfonimidoyl transfer is challenging.
Zn(II)‐Catalyzed Enantioselective Nucleophilic Substitution Reactions: Access to Sulfur(VI)‐Stereogenic Sulfonimidate Esters
Conflict of Interests The authors declare no conflict of interest. Data Availability Statement The data that support the findings of this study are available from the corresponding author upon reasonable request. Supporting Information Filename Description anie70479-sup-0001-SuppMat.pdf19.7 MB Supporting Information anie70479-sup-0002-Data.zip897.7 KB Supporting Information References 1, Angew. Chem. Int. Ed. 2013, 52, 9399–9408. 2, , , , , , Angew. Chem. Int. Ed. 2017, 56, 4100–4109. 3, , , , Eur. J. Med.
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