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Carbene‐Catalyzed Asymmetric Acetalization to Access Chiral 3‐Aryloxyphthalides
Conflict of Interests The authors declare no conflicts of interest. Supporting Information Filename Description asia70025-sup-0001-SuppMat.pdf5 MB Supporting References 1, , Tetrahedron: Asymm. 1990, 1, 477. 2, , , , , , Angew. Chem., Int. Ed. 2020, 59, 13479. 3, , , , , , Chin. Chem. Lett. 2024, 35, 109229. 4, , J. Am. Chem. Soc. 2002, 124, 9328. 5, , J. Am. Chem. Soc. 1999, 121, 3543. 6, , Eur. J. Cell Biol. 1999, 78, 1. 7, , , , , , , , , , , Cell Stem Cell 2015, 16, 142. 8, , , , Food Addit. Contam. 2003, 20, 1077.
Regio- and stereoselective access to highly substituted vinylphosphine oxides via metal-free electrophilic phosphonoiodination of alkynes - Nature Communications
Abstract In general, the P-centered ring-opening of quaternary phosphirenium salts (QPrS) predominantly leads to hydrophosphorylated products, while the C-centered ring-opening is primarily confined to intramolecular nucleophilic reactions, resulting in the formation of phosphorus-containing cyclization products instead of difunctionalized products generated through intermolecular nucleophilic processes.
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