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Rare Earth Metal-Organic Complexes Constructed from Hydroxyl and Carboxyl Modified Arenesulfonate: Syntheses, Structure Evolutions, Ultraviolet, Visible and Near-Infrared Luminescence - Dalton Transactions (RSC Publishing)

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By Li-Hua Huo, Ying-Hui Xiao, Zhaopeng Deng, Zhi-Biao Zhu
| Royal Society of Chemistry Verified
The reaction of 2-hydroxyl-4-carboxylbenzenesulfonic acid (H3L) and rare earth (RE) metal nitrates together with two N-heterocyclic ligands gives rise to the formation of 38 complexes, namely, [La(H2L)2(ox)0.5(H2O)4]n•2nH2O (1-La) (ox = oxalate), [RE2(H2L)2 (ox)(H2O)12]•2(H2L)•8H2O (2-RE) (RE = Nd, Sm, Eu, Gd, Tb, Dy), [RE(SO4)(H2O)7]•(H2L)•3H2O (3-RE) (RE = Ho, Er, Tm, Yb, Lu and Y), [RE(L)(H2O)3]n•nH2O (4-RE) (RE = Er, Tm, Yb and Lu), [RE(L)(2,2’-bipy)(H2O)]n (5-RE) (RE = La, Pr, Nd, Sm,...
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