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Triketone-Modified Lignin and the Corresponding Biomass-Based Diketoenamine Resins: Synthesis and Properties
Taking advantage of the reaction between triketone and primary amine, (17) cross-linked products of OL-TK and TREN were prepared ( Scheme 2 ) through the thermal process mentioned in the Experimental Section . The lignin-based cross-linked resin with 2 times the excess primary amine was obtained and coded as OLTK-CR-2. OLTK-CR-2 showed a gel fraction of 95 wt % measured in dimethyl sulfoxide (DMSO) at 25 °C to demonstrate its highly cross-linked structure.
Gel polymer electrolytes based on single-ion conducting polyelectrolyte (SICP) and SICP-functionalized carbon nanotubes
Gel polymer electrolytes based on single-ion conducting polyelectrolyte (SICP) and SICP-functionalized carbon nanotubes Single-ion conducting polyelectrolytes (SICPs) functionalized multiwalled carbon nanotubes (MWCNT-SICP) were prepared.
Radical 1,4-aryl migration enables nickel-catalysed remote cross-electrophile coupling of β-bromo amino acid esters with vinyl triflates
Radical 1,4-aryl migration enables nickel-catalysed remote cross-electrophile coupling of β-bromo amino acid esters with vinyl triflates A radical 1, 4-aryl migration enabling cross-electrophile coupling reaction toward remote transalkylation of N-benzyl alanine has been reported. In this strategy, with the occurrence radical-mediated Turce-Smiles rearrangement, the key α-aminoalkyl radicals are generated.
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