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Integrating the Substituent Effect into the Wade-Mingos Rules for Dicarboranes
Introduction In chemistry, several well-established rules are used to predict bonding, reactivity, stability, or aromaticity. Classical rules such as the octet and 18-electron rules are generally effective for describing molecular structures.
Metal-organic frameworks with two different-sized aromatic ring-confined nanotraps for benchmark natural gas upgrade
Metal–organic frameworks with two different-sized aromatic ring-confined nanotraps for benchmark natural gas upgrade† Recovery of light alkanes from natural gas is of great significance in petrochemical production. Herein, a promising strategy utilizing two types of size-complementary aromatic ring-confined nanotraps (called bi-nanotraps here) is proposed to efficiently trap ethane (C2H6) and propane (C3H8) selectively at their respective sites.
Spatially Confined π‐Complexation within Pore‐Space‐Partitioned Metal-Organic Frameworks for Enhanced Light Hydrocarbon Separation and Purification
Conflict of Interest The authors declare no conflict of interest. Supporting Information Filename Description smll202311555-sup-0001-SuppMat.pdf6.7 MB Supporting Information smll202311555-sup-0002-cif.zip353.9 KB Supporting Information References 1a) , , Nature 2016, 532, 435; b) , , , , , , Top. Curr. Chem. 2019, 377, 33. 2a) , , , , , , Coord. Chem. Rev. 2023, 484, 215111; b) , , , , , , , , , , , , , , , , , Science 2020, 368, 1002. 3a) , , , , Acc. Chem. Res. 2023, 56, 2569; b) , , , , Acc. Chem. Res.
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