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Construction and characterization of rare earth complexes for efficient emission tuning by tetraethyl ethylenebisphosphonate and tridentate chelating nitrogen ligands
Construction and characterization of rare earth complexes for efficient emission tuning by tetraethyl ethylenebisphosphonate and tridentate chelating nitrogen ligands Lanthanide nitrate and tetraethyl ethylenebisphosphonate reacted with TPY (1-9) and TPTZ (10-12) in acetonitrile ethanol mixture (1-9) and acetonitrile methanol mixture solution (10-12), respectively, to synthesize twelve new lanthanide complexes: {[Ln(NO3)3TPY]2L} (Ln=La (1), Ce (2), Pr (3), Nd (4), Sm (5), Eu (6)),...
Facile fabrication and characterization of rare-earth complexes based on Keggin-polyoxometalate with highly efficient activity for photocatalytic degradation of MO
Facile fabrication and characterization of rare-earth complexes based on Keggin-polyoxometalate with highly efficient activity for photocatalytic degradation of MO Using phosphotungstic acid, tetraethyl ethylenebisphosphonate (L) and rare earth chloride as raw materials, a series of Keggin-type POMs based rare earth complexes were synthesized by heating and stirring method: [LnL3(H2O)]PW12O40·CH3CN (1-6) (Ln= Dy, Ho, Er, Tm, Yb, Lu).
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