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Low curvature combined with high amorphization improves SERS sensitivity of semiconducting Rh–Se mesoporous nanospheres toward non-adsorbing resistant pollutants
Abstract Amorphous metal–selenium (M–Se) alloys hold promise for applications such as catalysis, electronics, and surface-enhanced Raman spectroscopy (SERS) sensing due to their surface reactivity, isotropic properties, and tunable bandgap. However, controlling the synthesis of nanostructured noble-metal-based M–Se materials is difficult, as the strong metallic bonding and low chemical reactivity of noble metals hinder homogeneous selenization.
Penas Ibáñez, M.ª Azucena. Los verbos frasales. Madrid: Arco/Libros-La Muralla, 2025. 116 pp. (ISBN: 978-84-7133-959-1)
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Solvent Evaporation Induced Micelle Assembly for Continuous Mesoporous Amorphous Metal-Organic Framework Films
Conflict of Interest The authors declare no conflict of interest. Supporting Information Filename Description adma71112-sup-0001-SuppMat.docx18.7 MB Supporting Information adma71112-sup-0002-MovieS1.mp438.3 MB Supplemental Movie 1 adma71112-sup-0003-MovieS2.mp437.6 MB Supplemental Movie 2 References 1, J. Am. Chem. Soc. 1994, 116, 7941. 2, Chem. Commun. 1996, 1149. 3, , , , , , , , , , , Nature 1997, 389, 364. 4, , , , Nat. Rev. Mater. 2019, 4, 775. 5, , , , , , , , , , , , ACS Nano 2024, 18, 22404.
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