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Electrochemical Ni–H Catalysis for Selective Tail-to-Tail Reductive Dimerization of Terminal Alkynes to 2,3-Dibranched Butadienes Reductive dimerization of terminal alkynes offers a direct route to diverse 1,3-diene frameworks, including linear, 1,3-, and 2,3-branched structures. Achieving precise regioselectivity, particularly for 2,3-dibranched butadienes, remains a significant challenge.
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