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Articles

Control of the Rectifying Effect and Direction by Redox Asymmetry in Rh2-Based Molecular Diodes

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By Donglei Bu, Yingqi Xiong, Yingning Tan, Miao Meng
| Royal Society of Chemistry Verified
D. Bu, Y. Xiong, Y. Tan, M. Meng and C. Y. Liu, Chem. Commun., 2018, Accepted Manuscript , DOI: 10.1039/C8CC02062K If you are not the author of this article and you wish to reproduce material from it in a third party non-RSC publication you must formally request permission using RightsLink. Go to our Instructions for using RightsLink page for details.
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Understanding the Charge Transport Properties of Redox Active Metal-Organic Conjugated Wires

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By Miao Meng, Donglei Bu, Yingqi Xiong, Yingning Tan
| Royal Society of Chemistry Verified
Layer-by-layer assembly of dirhodium complex [Rh (O CCH ) ] (Rh ) with linear N,N‘-bidentate ligands pyrazine (L ) or 1,2-bis(4-pyridyl)ethene (L ) on gold substrate has developed two series of redox active molecular wires, (Rh L ) @Au and (Rh L ) @Au (n = 1 - 6). By controlling the number of assembling cycles, the molecular wires in the two series vary systematically in length, as characterized by UV-Vis spectroscopy, cyclic voltammetry and atomic force microscopy.
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