Yining Huang
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Computer Science > Computation and Language
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Probing Induced-Fit Acetylene Adsorption and Separation in a Flexible Ultramicroporous Framework by Multinuclear SSNMR Spectroscopy: Insights Beyond Crystallography Click to copy article link Article link copied!
Abstract Click to copy section linkSection link copied! This study investigates the molecular-level-induced-fit adsorption of acetylene (C2H2) and carbon dioxide (CO2) in sql-SIFSIX-bpe-Zn, a flexible, anion-pillared ultramicroporous metal–organic framework (MOF). Sql-SIFSIX-bpe-Zn undergoes distinct pressure-dependent phase transitions, enabling a high selectivity for C2H2 over CO2 and ethylene (C2H4).
Interplay between noble gases and MOFs: Insights from 129Xe and 83Kr NMR spectroscopy
Abstract Efficient separation and storage of radioactive noble gas isotopes [krypton-85 (85Kr) and xenon-131m/133/135 (131m/133/135Xe)] from off-gas during spent nuclear fuel reprocessing are vital for environmental protection and noble gas recovery. Metal-organic frameworks (MOFs) are promising adsorbents, yet atomic-level insights into Xe and Kr adsorption remain limited.
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