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Controlling the Helicity and Handedness of Polyaromatics with Isobenzofuranophane
Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
The Photochemistry and Photophysics of Benzoyl-Carbazole
The Photochemistry and Photophysics of Benzoyl-Carbazole Benzoyl-carbazole and its derivatives are considered a platform for exploring process such as Room Temperature Phosphorescence (RTP) and Thermally Activated Delayed Fluorescence (TADF). They are also reported to exhibit dual emission, but there is a great spectral variability in the relative intensity of the emission bands reported in different studies.
Controlling Helicene Pitch by Molecular Tethering
Controlling Helicene Pitch by Molecular Tethering We applied post-cyclization annulation to introduce a series of tethered S-shaped double [4]helicenes in which the intramolecular tether imposes a specific helical handedness. Introducing a tether and then shortening tether length incrementally increase the pitch angle of [4]helicene, thus enabling quantitative study of the effects of helicene’s pitch on its electronic and (chiro)optical properties.
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