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Yu-Ying Chuang

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Articles

Palladium‐Catalyzed Decarboxylative C─H Alkenylation of Proaromatic Acids With Allyl Alcohols and N‐Allyl Sulfonamides

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By Veerabhushanam Kadiyala, Prahallad Meher, Yin-Chia Lu, Yu-Ying Chuang
| Wiley Online Library Verified
We develop an efficient palladium-catalyzed decarboxylative C─H alkenylation of cyclohexa-2,5-dienyl carboxylic acids with allylic alcohols and N-allyl sulfonamides, enabling regioselective access to diverse vinylarenes. The transformation proceeds under mild, operationally simple conditions and tolerates a broad range of alkyl, aryl, and heteroaryl substituents. Mechanistic studies reveal that the reaction is going via carboxylate-directed C─H activation and olefin insertion step.
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