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A Twist in Electronic Relaxation of Pyrimidine Nucleosides and Nucleotides: Impact of C5 Methylation on Nonadiabatic Transition and Photohydration Damage Click to copy article link Article link copied!
Introduction Click to copy section linkSection link copied! The double helical structure of DNA, formed by adenine, thymine (Thy), guanine, and cytosine (Cyt), as proposed by Watson and Crick, (1) is essential for the storage and replication of genetic information. However, these nucleobases exhibit strong ultraviolet (UV) absorption bands around 260 nm and are consequently excited to the 1 ππ* states upon UV irradiation.
A Twist in Electronic Relaxation of Pyrimidine Nucleosides and Nucleotides: Impact of C5 Methylation on Nonadiabatic Transition and Photohydration Damage Click to copy article link Article link copied!
Introduction Click to copy section linkSection link copied! The double helical structure of DNA, formed by adenine, thymine (Thy), guanine, and cytosine (Cyt), as proposed by Watson and Crick, (1) is essential for the storage and replication of genetic information. However, these nucleobases exhibit strong ultraviolet (UV) absorption bands around 260 nm and are consequently excited to the 1ππ* states upon UV irradiation.
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