Yukichi Namioka on Muck Rack

Yukichi Namioka

As seen in: ACS Publications
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Articles

Synthesis of P-Modified DNA from Boranophosphate DNA as a Precursor via Acyl Phosphite Intermediates

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By Ayumi Igarashi, Yuhei Takahashi, Kiyoshi Kakuta, Yukichi Namioka
| ACS Publications
Abstract In this study, we successfully synthesized several kinds of P-modified nucleic acids from boranophosphate DNAs via an acyl phosphite intermediate in solution and on a solid support. In the solution-phase synthesis, phosphorothioate diester, phosphotriester, and phosphoramidate diester were synthesized in a one-pot reaction from boranophosphodiester via the conversion of an acyl phosphite as a key intermediate.
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