Yunnu Liu

Complexes of Th(iv) with neutral O–N–N–O hybrid ligands: a thermodynamic and crystallographic study† Yanqiu Yang, *a Lina Lv,ab Yunnu Liu,a Baihua Chen,a Jun Liu,a Xingliang Lia and Shunzhong Luo*a Author affiliations * Corresponding authors a Institute of Nuclear Physics and Chemistry, CAEP, Mianyang, Sichuan 621900, China E-mail: yan.qiu.yang@163.com, luoshzh@caep.cn b Fundamental Science on Nuclear Wastes and Environmental Safety Laboratory, Southwest University of Science and Technology,...

Complexes of Th(IV) with Neutral O-N-N-O Hybrid Ligands: A Thermodynamic and Crystallographic Study Yanqiu Yang, Lina Lü, Yunnu Liu, Bai-Hua Chen, Jun Liu, Xingliang Li and Shunzhong Luo Abstract Thermodynamics of Th(IV) complexes with N,N,N′,N′-tetramethyl-2,2′-bipyridine-6,6′-dicarboxamide (TMBiPDA) and N,N,N′,N′-tetramethyl-1,10-phenanthroline-2,9-dicarboxamide (TMPhenDA) in CH3OH/10%(v)H2O (CH3OH:H2O = 9:1 by volume) were determined by spectrophotometry and calorimetry.