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Hydrogen-bonding catalysis of sulfonium salts
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Hydrogen-bonding catalysis of sulfonium salts
a Department of Environmental Science, Graduate School of Fisheries and Environmental Sciences, Nagasaki University, 1-14, Bunkyo-machi, Nagasaki 852-8521, Japan E-mail: seijishirakawa@nagasaki-u.ac.jp b Department of Applied Molecular Chemistry, College of Industrial Technology, Nihon University, Izumi-cho, Narashino, Japan c Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan
Chiral quaternary phosphonium salts as phase-transfer catalysts for environmentally benign asymmetric transformations
Phase-transfer catalysis has been recognized as a powerful and green sustainable method for organic synthesis in both industry and academia. Since the pioneering studies on enantioselective phase-transfer reactions promoted by cinchona alkaloid-derived tetraalkylammonium salt catalysts, this research field has served as an attractive area for the pursuit of green sustainable chemistry.
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