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Photocatalytic Synthesis of 2-Oxabicyclo[2.1.1]hexanes: Cobalt-Enhanced Efficiency Development of new synthetic strategies in the synthesis of preparing C(sp3)-rich arene bioisosteres, especially their heteroatom incorporated analogs are less explored, but highly in demand. Here we report a photocatalytic [2π+2σ] cycloaddition reaction between bicyclo[1.1.0]butanes and aldehydes enabled by cobalt under visible light irradiation.
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