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Inorganic ligand-supported Mo oxide as a hydrogen atom transfer photocatalyst for direct C(sp2)−H phosphorylation Visible-light-induced C(sp2)−H phosphorylation of 2H-thiozoles/quinoxalines with H-phosphine oxides was achieved by using an inorganic-ligand supported Mo oxide ([N(C4H9)4]2[Mo6O19]) as a hydrogen atom transfer (HAT) photocatalyst.
Aerobic Oxidative C-H Phosphorylation of Quinoxalines under Catalyst-free Conditions We herein report one direct and efficient protocol on phosphorylation of quinoxalines, which employs aerobic oxygen as the green oxidant under catalyst-free conditions. This methodology represents one of the most environmental-friendly and easily-handled protocols, providing a series of phosphorylated quinoxalines in good to excellent yields.
Research Article Dedicated to Professor Youqi Tang, Peking University, on the occasion of his 100th birthday PDF ShareShare Abstract A Pd‐catalyzed regio‐ and stereoselective alkynylallylation of a specific C−C σ bond in cyclopropenes, using allyl propiolates as both allylation and alkynylation reagents, has been achieved for the first time.
Research Article Dedicated to Professor Youqi Tang, Peking University, on the occasion of his 100th birthday PDF ShareShare Abstract A Pd‐catalyzed regio‐ and stereoselective alkynylallylation of a specific C−C σ bond in cyclopropenes, using allyl propiolates as both allylation and alkynylation reagents, has been achieved for the first time.
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