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Articles

TD-Interpreter: Enhancing the Understanding of Timing Diagrams with Visual-Language Learning

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By Vincent Willem, Zhantao Yang, Ezio Bartocci, Meixun Qu
| arxiv.org
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Catalyst Free Annulative Thioboration of Unfunctionalized Olefins

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By Chun-hua Yang, Shiqi Chen, Zhantao Yang, Xixi Chen
| Royal Society of Chemistry Verified
A direct and catalyst-free annulative thioboration of unfunctionalized olefins has been developed. In the presence of BCl3 as the sole boron source, the boryl group and thiol group are added to the C-C double bonds simultaneously. After hydrolysis, the corresponding ((tetrahydrothiophen-2-yl)methyl)boronic acid, ((tetrahydro-2H-thiopyran-2-yl)methyl)boronic acid, ((2,3-dihydrobenzo[b]thiophen-2-yl)methyl)boronic acid and (thiomorpholin-2-ylmethyl)boronic acid are obtained with good yield.
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