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[2512.00907] Magnetic Tactile-Driven Soft Actuator for Intelligent Grasping and Firmness Evaluation
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Direct conversion of various phosphate sources to a versatile P-X reagent [TBA][PO2X2] via redox-neutral halogenation - Nature Communications
Abstract Inorganic phosphates hold significant potential as ideal natural building blocks, forming a fundamental basis for organic and biochemical synthesis. However, their limited solubility, inherent chemical stability, and low reactivity pose substantial challenges to converting phosphates into organophosphates under mild conditions.
Synthesis of 2-Fluorinated Pyrazolo[1,5-a]pyridines via Base- Mediated [3+2] Cycloaddition of N-Aminopyridinium Salts with gem-Difluorostyrenes
Synthesis of 2-Fluorinated Pyrazolo[1,5-a]pyridines via Base- Mediated [3+2] Cycloaddition of N-Aminopyridinium Salts with gem-Difluorostyrenes A method for the construction of 2-fluoropyrazolo[1,5-a]pyridines through base-promoted [3+2] cycloaddition reaction of N-aminopyridinium salts with gem-difluorostyrenes has been established. A range of N-heterocycles with 2-fluorinated pyrazo[1,5-a]pyridines were efficiently obtained in moderate to good yields.
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