Ziyin Kong

Buy Article Permissions and Reprints All articles of this category A practical method is introduced for the catalytic conversion of terminal alkynes into α-substituted vinyl boronic esters. The process employs catalytic amounts of nanoparticle-supported gold catalysts and catalytic amounts of copper to effect the overall transformation. boron - cross-coupling - AuNPs - alkynes - protonation Supporting information for this article is available online at https://doi.org/10.1055/s-0043-1774906.

Communication Prof. James P. Morken Corresponding Author E-mail address: morken@bc.edu http://orcid.org/0000-0002-9123-9791 Department of Chemistry, Boston College, 2609 Beacon Street, Chestnut Hill, MA, 02467 USA Search for more papers by this author Abstract Chiral 1,2‐bimetallic reagents are useful motifs in synthetic chemistry. Although syn ‐1,2‐bimetallic compounds can be prepared by alkene dimetallation, anti ‐1,2‐bimetallics are still rare.

Communication James Patrick Morken Corresponding Author E-mail address: morken@bc.edu Boston College, Dept. of Chemistry, 2609 Beacon Street, Merkert Chemistry Lab, 02467 Chestnut Hill, UNITED STATES Search for more papers by this author PDF PDF ShareShare Abstract Chiral 1,2‐bimetallic reagents are useful motifs in synthetic chemistry. Although  syn ‐1,2‐bimetallic compounds can be prepared by alkene dimetallation,  anti ‐1,2‐bimetallics are still rare.