The present work focuses on investigating the effect of superheated steam drying on supraparticle formation from nanosuspensions of colloidal silica (8, 20, and 95 nm) at 5, 15, and 30 wt%. The supraparticle formation is studied by single droplet drying at 105 °C, 200 °C, and 300 °C. It is shown that by increasing superheated steam temperature, single droplets reached the locking point earlier and bigger supraparticles are obtained.