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From 2D MXenes to 3D Carbides: Transformation of Ti 3 C 2 T z Thin Films into TiC x Carbide Nanolayers Click to copy article link Article link copied!
MXenes are 2D transition-metal carbides, nitrides, or carbonitrides, typically synthesized by HF- or molten salt etching of a parent MAX phase metallic A-layer, followed by intercalation (e.g., alkali ions like Li+ or Na+, or organic molecules), and exfoliation. (1) During synthesis, MXenes surfaces acquire an abundance of termination groups (e.g., −O, −OH, −F, −Cl) with their chemistry depending on the synthesis process.
Synthesis of Ti1‐xWx Solid Solution MAX Phases and Derived MXenes for Sodium‐Ion Battery Anodes
1 Introduction MAX phases are a diverse family of atomically-layered compounds that follow the formula Mn+1AXn.[1, 2] Where n is a positive integer (typically 1 to 4), M represents an early transition metal, A represents a group-A element, typically from groups 13 and 14 of the periodic table, and X is either carbon and/or nitrogen.
Improved Durability of Ti3C2Tz at Potentials above the Reversible Hydrogen Electrode by Tantalum Substitution (Adv. Funct. Mater. 10/2024)
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