Mark Baranov
As seen in:
Nature,
Wiley Online Library,
MDPI,
ACS Publications,
The Times of Israel,
Royal Society of Chemistry,
QOSHE
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Harnessing microalgae for the biosynthesis of molecular crystals - Nature Biotechnology
Abstract Highly reflective biogenic crystals such as guanine have potential as biocompatible alternatives to toxic inorganic optical materials. However, controlling the structural and optical properties of these sparingly soluble crystals in vitro is challenging. Engineered microbial cells have been used widely to generate high-value metabolites, but the biosynthesis of functional crystalline materials has not been achieved.
Ion-Size Controlled Non-Classical Crystallization of Metal-Oxide Nanoparticles Covered with a Few Highly Charged Ligands
Preparation of POM-Complexed NCs POM-complexed ε-MnO 2 NCs 1 ( Figure 1 a) were prepared by adding MnO 4– to a hot aqueous solution of [AlCr III W 11 O 39 ] 6– , and refluxing under air for 2 h (see Experimental section and Figure S1 ). After workup, the yield of 1 was 46.2%, based on Mn. Cryo-TEM images of these samples revealed individual particles with an average size of 2.7 ± 0.2 nm ( Figure 1 b and Figure S2 ). Figure 1 Figure 1. Characterization of the core and ligands of 1.
Ion-Size Controlled Non-Classical Crystallization of Metal-Oxide Nanoparticles Covered with a Few Highly Charged Ligands
Introduction Click to copy section linkSection link copied! In recent decades, a wide variety of ligand-stabilized NPs have been prepared and crystallized into many different superlattices (SLs), (1−7) and even quasicrystals. (8) Through combined experimental and modeling studies, (9) it has been revealed (5) how the NP type and morphology, (10) ligand type and size, (2) NP concentration, solvent type, and temperature (11−13) can affect the crystalline phase (12) and polymorphism.
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