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Bart de Nijs on Muck Rack

Bart de Nijs

As seen in: Nature, PNAS, Science Magazine, Physical Review B
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Articles

Transient Au–Cl adlayers modulate the surface chemistry of gold nanoparticles during redox reactions - Nature Chemistry

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By Sarah May Sibug-Torres, Elle W. Wyatt, Rakesh Arul, Tabitha Jones, Duncan Graham, Bart de Nijs, Oren A. Scherman, Reshma R. Rao, Alexander G. Squires, David Scanlon, Hatef Sadeghi, Nicolas Spiesshofer
| Nature Verified
Abstract Controlling surface chemistry at the nanoscale is essential for stabilizing structure and tuning function in plasmonic, catalytic and sensing systems, where even trace ligands or ions can reshape surface charge and reactivity. However, probing such dynamic interfaces under operando conditions remains challenging, limiting efforts to engineer nanomaterials with precision.
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Alchemically-glazed plasmonic nanocavities using atomic layer metals: controllably synergizing catalysis and plasmonics - Nature Communications

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By Shu Hu, Qianqi Lin, Bart de Nijs
| Nature Verified
Abstract Plasmonic nanocavities offer exceptional confinement of light, making them effective for energy conversion applications. However, limitations with stability, materials, and chemical activity have impeded their practical implementation. Here we integrate ultrathin palladium (Pd) metal films from sub- to few- atomic monolayers inside plasmonic nanocavities using underpotential deposition.
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Uncovering low-frequency vibrations in surface-enhanced Raman of organic molecules - Nature Communications

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By Bart de Nijs, Ruben Esteban, Fernando Aguilar-Galindo, Edina Rosta, Javier Aizpurua, Roberto A. Boto
| Nature Verified
Abstract Accessing the terahertz (THz) spectral domain through surface-enhanced Raman spectroscopy (SERS) is challenging and opens up the study of low-frequency molecular and electronic excitations. Compared to direct THz probing of heterogenous ensembles, the extreme plasmonic confinement of visible light to deep sub-wavelength scales allows the study of hundreds or even single molecules.
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