Brandon R Barnett
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Synthesis and characterization of trigonal monopyramidal complexes of divalent manganese
Advanced search Journal of Coordination Chemistry Latest Articles Submit an article Journal homepage Full Article Figures & data References Supplemental Citations Metrics Reprints & Permissions Read this article /doi/full/10.1080/00958972.2025.2495055?needAccess=true Abstract Bio-inspired studies of manganese coordination chemistry often seek to replicate features within the secondary coordination sphere of manganese-bearing metalloenzymes through judicious ligand design.
Generation and Reactivity of a High-Spin Iron(IV)-Oxo Complex That Is Stable at Ambient Temperatures
The impressive activities and selectivities exhibited by many native metalloenzymes are connected to their abilities to confine reactive species within well-defined microenvironments. (1) Obviating deleterious reactions of high-energy intermediates is accomplished, in part, by isolating the active site from the exterior environment.
Generation and Reactivity of a High-Spin Iron(IV)-Oxo Complex That Is Stable at Ambient Temperatures
The impressive activities and selectivities exhibited by many native metalloenzymes are connected to their abilities to confine reactive species within well-defined microenvironments. (1) Obviating deleterious reactions of high-energy intermediates is accomplished, in part, by isolating the active site from the exterior environment.
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