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Secondary batteries are essential for powering a wide array of modern technologies, including smartphones, electric vehicles, autonomous aircraft, and robotics. As these technologies advance, the demands on batteries become increasingly complex. Next-generation secondary batteries must meet higher operating voltages and enhanced energy densities [1], [2], [3], [4].
Lithium-ion batteries (LIBs) have experienced booming growth in the last three decades and become indispensable in distributed energy storage, portable electronic products, and electrical vehicles [1], [2]. However, more urgent requirements for higher energy density have recently been brought to the LIBs [3].
Aqueous zinc ion batteries (AZIBs) have attracted extensive attention due to their abundant Zn metal resources, high theoretical capacity (820 mAh/g), appropriate redox potential (−0.762 V vs. SHE), low cost and environmental friendliness [1], [2], [3].
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