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The effect of sodium content on sodium diffusion in NaxTi0.2Mn0.2Fe0.2Co0.2Ni0.2O2 high-entropy layered oxide - Journal of Solid State Electrochemistry

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By Mechanochemistry SB RAS, Far-Eastern Branch
| link.springer.com
Abstract The series of O3-type high-entropy layered oxides NaxTi0.2Mn0.2Fe0.2Co0.2Ni0.2O2 were prepared by the mechanochemically assisted solid-state synthesis and studied as cathode materials for sodium-ion batteries. The effect of sodium excess (0, 10, and 20%) on electrochemical performance was investigated. It has shown that the addition of 10 or 20% excess sodium leads to a deterioration in rate performance despite a slight increase in specific capacity at low cycling rates (below 2C).
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