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Hai-Xiang Gao

As seen in: Nature, Wiley Online Library
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Articles

Unlocking the reactivity of difluoroketene and its synthetic applications

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By Chi Zhang, Liying Fu, Hai-Xiang Gao, Wenjing Jia, Hongrui Zhang, Yuting Liu, Xue-Qiang Chu, Yu Zhang, Kai Guo, Chao Feng
| Nature Verified
Abstract Discovery and application of reactive intermediates has prominently expedited the development of organic chemistry. In this respect, while ketene has been well recognized as a versatile intermediate for a wide range of transformations, practical application of difluoroketene remained virtually unrealized because of its highly reactive nature. Herein, we present a transition-metal-free approach for in situ generation of difluoroketene using difluorobromoacetylsilane as a precursor.
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Photoredox-Catalyzed Strain-Release-Driven Aminopyridylation of Bicyclo[1.1.0]butanes with N-Aminopyridinium Ylides

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By Hai-Xiang Gao, Yuanhang Li, Mengyu Wu, Xiaoyu Zhu
| dx.doi.org
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Stereoselective Photoredox Catalyzed (3+3) Dipolar Cycloaddition of Nitrone with Aryl Cyclopropane

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By Yao Xu, Hai-Xiang Gao, Chengkai Pan, Yue Shi
| Wiley Online Library Verified
Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Filename Description anie202310671-sup-0001-misc_information.pdf11.5 MB Supporting Information References 1, , Angew. Chem. Int.
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