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Tautomeric Forms of 2-Hydroxynaphthalene-Based Imines: Theoretical and Experimental Comparisons
Abstract Click to copy section linkSection link copied! Experimental and theoretical studies on two 2-hydroxynaphthalene imine-based compounds, namely, 1-[{(2,4-dichlorophenyl)imino}methyl]naphthalen-2-ol (24Clmno) and (E)-N-(2,4-dichlorophenyl)-2-{(2-hydroxynaphthalen-1-yl)methylene}hydrazine-1-carbothioamide (24Clhhc), to establish the energetically favorable enol-imine form in their respective crystal structures are reported.
See-Saw Ni(II) thiosemicarbazones, Energy and Photophysical Properties
See-Saw Ni(II) thiosemicarbazones, Energy and Photophysical Properties Depending on the orientation and nature of substituents, the properties of metal complexes decorated at the external periphery change. In this study, we present the synthesis, characterization, and emission properties of three thiosemicarbazone-based nickel complexes.
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