Ke-Yin Ye

Supporting Information Filename Description cjoc202500936-sup-0001-supinfo.pdfPDF document, 10.9 MB Appendix S1: Supporting Information References 1 ; ; ; Sulfur(VI) Fluoride Exchange (SuFEx): Another Good Reaction for Click Chemistry. Angew. Chem. Int. Ed. 2014, 53, 9430–9448. 2(a) ; ; ; ; ; The Growing Applications of SuFEx Click Chemistry. Chem. Soc. Rev. 2019, 48, 4731–4758; (b) ; Sulfonyl fluorides as targets and substrates in the development of new synthetic methods. Nat. Rev. Chem.

Sulfonation of aromatic compounds is an essential process in the production of a wide range of commercial products or intermediates in the scope of surfactants, detergents, and pharmaceuticals [[1], [2], [3], [4]]. Traditionally, these sulfonation reactions are conducted with oleum. A disadvantage of oleum is its strong oxidizing power, leading to gummy tar-like byproducts [5].

Electrochemical synthesis of vicinal azidoacetamides† Yi Yu,a Yaofeng Yuan a and Ke-Yin Ye *a Abstract Vicinal diamines are an important structural motif in bioactive natural products and pharmaceutical intermediates. Herein, an environmentally friendly and efficient electrochemical approach to azidoacetamides, as one variant of vicinal diamines, has been developed.