Introduction Click to copy section linkSection link copied! Atropisomerism is a stereochemical feature that arises from the high configurational stability of chiral axes, and is an important consideration in the synthesis of chiral ligands, (1) molecular devices, (2) and drug candidates. (3) As such, understanding how specific molecular features influence the configurational stability of chiral axes, (4) and synthetic methods for their construction, (5) is of high interest.