Correction to: Nature Materials https://doi.org/10.1038/s41563-026-02662-y, published online 3 July 2026. In the version of the article initially published, in the “Topology and cage confinement” section, “…collectively generating a 2,3,6-connected ith-d topology” should have read “…collectively generating a 3,6-connected ith-d topology”. This correction has been made to the HTML and PDF versions of the article. About this article Tang, X., Wang, X., Ye, ZM. et al.
Abstract Controlling local chemical environments within porous crystalline materials is essential for selective adsorption and catalysis, yet remains difficult in stable frameworks with precisely oriented functional sites. Here we use reticular chemistry to programme tunable confinement in triazolate metal–organic frameworks constructed from Kuratowski-type Zn5Cl4 nodes.
Abstract Electrified CO2 capture and release from air offers net-negative emissions, but today’s liquid-carbonate-based systems have a high energy cost (6–10 GJ per ton of CO2), and organic sorbents are oxygen sensitive.
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