Paul Chirik on Muck Rack

Paul Chirik

  • Editor-in-chief, ORGANOMETALLICS
Princeton
As seen in: Color Research & Application, Nature, Wiley Online Library, ACS Publications, Analytical Chemistry, Science Magazine, Royal Society of Chemistry, Cell Press, Chemistry World
Chemist
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Articles

A Tutorial on the Mechanisms of Group 9 Transition-Metal-Catalyzed Asymmetric Olefin Hydrogenation Click to copy article link Article link copied!

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By Lauren Mendelsohn, Paul Chirik
| dx.doi.org
Introduction Click to copy section linkSection link copied! The asymmetric hydrogenation of olefins is one of the most powerful and widely used methods for the synthesis of enantioenriched products. (1) This is in part due to the discovery and implementation of highly active and enantioselective catalysts, as well as the prevalence of C–H bonds in stereocenters in active pharmaceutical ingredients.
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A Tutorial on the Mechanisms of Group 9 Transition-Metal-Catalyzed Asymmetric Olefin Hydrogenation Click to copy article link Article link copied!

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By Lauren Mendelsohn, Paul Chirik
| ACS Publications
Evidence for Unsaturated Pathways in Rhodium-Catalyzed Asymmetric Hydrogenation The earliest mechanistic studies for hydrogenation with cationic bis(phosphine) rhodium catalysts support an unsaturated pathway. Experimental efforts were conducted independently by Halpern and Brown and relied on less donating achiral bis(phosphine) ligands.
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Telescoped Nickel-Catalyzed Borylation-(Phenoxyimine)Nickel-Catalyzed C(sp2)–C(sp3) Suzuki–Miyaura Coupling for Afimetoran Core Synthesis

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By Gregory L. Beutner, Paul Chirik, William Gallagher , L. Reginald Mills
| dx.doi.org
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