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Xiao Cai

As seen in: Nature, Wiley Online Library, Memory Studies, ScienceDirect, MDPI, Canadian Journal of Infectious Diseases & Medical Microbiology, Anti-Corrosion Methods and Materials

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Articles

Atomically precise Au 8 Pd 1 (DPPF) 4 2+ catalyst orchestrates the synthesis and utilization of hydrogen peroxide

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By Xiao Cai, Jun Yao, Shuangshuang Huang, Yan Zhu
| Nature Verified
Abstract Atomically precise metal clusters that merge structural clarity, functional modularity, and tunable spatial programmability have gained momentum over the past decade. Here, we report the catalysis of an atomically precise Au8Pd1(DPPF)42+ (DPPF = 1,1’-bis(diphenylphosphino)ferrocene) cluster in the synthesis and utilization of hydrogen peroxide.
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Analysis of ultrasound Doppler flow pattern recognition method for drilling gas intrusion monitoring

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By Qingfeng Guo, Xiao Cai, Lijun Geng, Pengfei Li, Qing Liu, Minglei Men, Guolang Shen
| Nature Verified
Abstract High-pressure gas intrusion during drilling operations poses significant well control challenges, heightening blowout risks. To address this critical safety concern, this paper proposes a real-time monitoring framework by characterizing gas–liquid flow pattern transitions through ultrasonic Doppler detection and time–frequency analysis.
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Photochemical synthesis of oxiranes using DABSO-activated sulfinates and allylic peroxides

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By Ziyang Li, Huiwen Zheng, Zou Chen, Jiangtao Lin, Zhiming Zhu, Ligang Huang, Xiao Cai, Jiang Duan, Qing Sun, Chao Shu
| Nature Verified
Abstract The family of oxiranes encompasses a variety of compounds with extensive applications across different fields. Herein, we report the development of a visible-light irradiation method using sulfinates in the presence of DABSO to form sulfonyl radicals, which results in the efficient sulfone-epoxidation of allylic peroxides, directly accessing a considerable range of highly functionalized strained oxiranes.
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