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Distortion-engineered C 1 -symmetric inorganic molecular cages enable tunable chiroptical nonlinear optics with broad infrared transparency
Abstract Chiroptical materials combining chirality with second-harmonic generation are attractive for polarization-resolved photonics, yet examples integrating strong chiroptical nonlinear activity, broad infrared transparency and inorganic robustness remain limited. Here we report a purely inorganic strategy in which molecular-level geometric distortion of intrinsically C1-symmetric phosphorus–chalcogen cages tunes second-harmonic generation circular dichroism (SHG-CD).
Unravelling the charge transfer and kinetics of BiVO4 by Co dopant and NiFeOx co-catalyst for efficient photoelectrochemical water splitting
Unravelling the charge transfer and kinetics of BiVO4 by Co dopant and NiFeOx co-catalyst for efficient photoelectrochemical water splitting† Understanding the kinetic mechanism for charge transfer and reaction involved in the photoelectrochemical (PEC) process of BiVO4-based photoanodes is key to designing better photoelectrodes in solar water splitting.
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