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Photo-DAC: Light-Driven Ambient-Temperature Direct Air Capture by a Photobase
Photo-DAC Design Implementation of the photo-DAC cycle proposed in Figure 1 requires a functional photobase (PB) and a matching sorbent (S) that satisfy several criteria. First, the selected PB needs to have a sufficiently wide p Ka swing between its photoexcited and dark states to allow CO 2 capture and release under DAC conditions.
Photo-DAC: Light-Driven Ambient-Temperature Direct Air Capture by a Photobase
Journal of the American Chemical Society Cite this: J. Am. Chem. Soc. 2026, XXXX, XXX Click to copy citationCitation copied! . This publication is licensed under CC-BY-NC-ND 4.0 . You are free to share (copy and redistribute) this article in any medium or format within the parameters below: Creative Commons (CC): This is a Creative Commons license. Attribution (BY): Credit must be given to the creator. Non-Commercial (NC): Only non-commercial uses of the work are permitted.
Front Cover: Accessing Transient Isomers in the Photoreaction of Metastable‐State Photoacid (ChemPhysChem 13/2025)
May Waters Chemical Sciences Division, Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, TN, 37831 USA Department of Chemistry, Michigan Technological University, Houghton, MI, 49931 USA Search for more papers by this author
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