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Imidazolyl Phosphine as Versatile Hemilabile Ligand: Synthesis and Characterization of a New Tetracationic Au20 Nanocluster
Conflict of Interests The authors declare no conflict of interest. Supporting Information Filename Description asia70050-sup-0001-SuppMat.docx7.6 MB Supporting Information References 1, , Coord. Chem. Rev. 1991, 108, 27–110. 2, , Angew. Chem., Int. Ed. 2001, 40, 680–699. 3, , Inorg. Chem. 1979, 18, 2658–2666. 4, Angew. Chem., Int. Ed. 2008, 47, 1814–1818. 5, , , , , , Coord. Chem. Rev. 2021, 446, 214120. 6, , Coord. Chem. Rev. 2018, 355, 150–172. 7, , , , , , , , Nat. Rev. Mater. 2025, 10, 89.
Halide‐Directed Ligand Engineering Enables Expedient, Controlled and Divergent Syntheses of Diphosphine‐Protected Au Nanoclusters
Conflict of Interest The authors declare no conflict of interest. Supporting Information Filename Description smll202500189-sup-0001-SuppMat.docx26.4 MB Supporting Information smll202500189-sup-0002-SuppMat.cif16.5 MB Supporting Information smll202500189-sup-0003-SuppMat.cif22.4 MB Supporting Information References 1, , Nat. Rev. Mater. 2023, 8, 372. 2, , , , , , , , Aggregate. 2022, 4, e255. 3, , , , , , , , Nat. Rev. Mater. 2025, 10, 89. 4, , Small. 2019, 15, 1902703. 5, , , , , Mater. Chem. Front.
Nuclearity enlargement from [PW9O34@Ag51] to [(PW9O34)2@Ag72] and 2D and 3D network formation driven by bipyridines - Nature Communications
Abstract The structural transformations of metal nanoclusters are typically quite complex processes involving the formation and breakage of several bonds, and thus are challenging to study. Herein, we report a case where two lacunary Keggin polyoxometallate templated silver single-pods [PW9O34@Ag51] (SD/Ag51b) fuse to a double-pod [(PW9O34)2@Ag72] by reacting with 4,4’-bipyridine (bipy) or 1,4-bis(4-pyridinylmethyl)piperazine (pi-bipy).
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