Federico Barbieri
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Operando NMR Monitoring of Electrochemical Reactions Click to copy article link Article link copied!
Introduction Click to copy section linkSection link copied! Electrochemistry has recently emerged as a powerful strategy in synthetic chemistry for the construction of valuable chemical motifs. (1) The ability to generate highly reactive radical and radical ion intermediates in a controllable manner under mild, environmentally friendly conditions has inspired the development of numerous electrochemical methodologies for diverse transformations.
The Laurencia Stereochemical Paradox: Chemical Shift Litmus Test, Asymmetric Total Synthesis, and Structural Reassignment of (+)-Itomanallene B
The Journal of Organic Chemistry Cite this: J. Org. Chem. 2026, XXXX, XXX Click to copy citationCitation copied! Learn about these metrics Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days. Citations are the number of other articles citing this article, calculated by Crossref and updated daily.
The Laurencia Stereochemical Paradox: Chemical Shift Litmus Test, Asymmetric Total Synthesis, and Structural Reassignment of (+)-Itomanallene B
Abstract Click to copy section linkSection link copied! Red algae of the genus Laurencia are prolific sources of halogenated C15-acetogenins, many of which contain a tetrahydrofuran (THF) ring and a bromoallene terminus. Among them, Itomanallene B-type metabolites have presented a stereochemical paradox, as Laurencia intricata and Laurencia nangii yield epimeric structures despite sharing the same planar connectivity.
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