Yinlong Zhu
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Hydroxyl-rich nanocavities on perovskite enable nearly barrierless intramolecular hydrogen transfer for nitrate electroreduction to ammonia
Abstract Electrocatalytic nitrate reduction to ammonia (NITRR) provides a sustainable avenue for simultaneous nitrate mitigation and ammonia synthesis, but the sluggish surface hydrogen migration during NITRR remains a major bottleneck. Here, we show a barrierless hydrogen transfer pathway along intramolecular hydrogen bonds between hydroxyls of hydroxyl-rich nanocavities for efficient nitrate electroreduction to ammonia.
Trifunctional electrocatalyst with accurate surface reconstruction for zinc-air batteries and water electrolyzers
Abstract Exploiting cost-effective trifunctional electrocatalysts toward oxygen evolution reaction, hydrogen evolution reaction and oxygen reduction reaction is important for sustainable energy conversion and storage devices yet challenging. Here, we report a single-phase trifunctional electrocatalyst Sr2CoRuO6-δ with well-defined super-exchange double perovskite structure, which can efficiently catalyze oxygen evolution, hydrogen evolution and oxygen reduction under alkaline conditions.
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