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Apparao M. Rao

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Articles

Solvation engineering decouples bulk and interfacial chemistry for robust potassium-ion batteries

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By Dianwei Zhang, Hongwei Fu, Xuemei Ma, Apparao M. Rao, Yihan Yang, Fuxiang Li, Xiazhen Li, Jiang Zhou, Bingan Lu
| Nature Verified
Abstract The development of high-performance potassium-ion batteries is constrained by the intrinsic trade-off between bulk and interfacial electrolyte properties, a dilemma exacerbated under harsh operating conditions. Here we report a solvation structure engineering strategy to decouple these conflicting factors, breaking this trade-off while enabling non-flammability, stable, and fast-cycling performance in batteries.
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Oxygen 2p Band Pinning Stabilizes High‐Voltage Potassium‐Ion Batteries

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By Jie Chen, Hongwei Fu, Apparao M. Rao
| Wiley Online Library Verified
1 Introduction Amid growing demand for large-scale energy storage systems, intensive research into high-performance battery technology with the characteristic of low cost is spurring [1-14]. Among the secondary ion batteries, potassium-ion batteries (PIBs) have attracted significant interest due to the natural abundance of potassium resources and the low redox potential of K+/K (−2.93 V vs SHE) [15-23].
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In Situ Construction of Uniform and Elastic Solid-Electrolyte Interphase for High‐Performance Potassium Batteries

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By Mingyuan Gu, Hongwei Fu, Apparao M. Rao, Jiang Zhou
| Wiley Online Library Verified
Conflict of Interest The authors declare no conflict of interest. Supporting Information Filename Description adfm202407867-sup-0001-SuppMat.pdf2.1 MB Supporting Information References 1, , , , , , , Adv. Funct. Mater. 2020, 30, 1909887. 2, , , Energy Environ. Sci. 2020, 13, 4583. 3, , , Joule 2021, 5, 1119. 4, , , , , Angew. Chem., Int. Ed. 2019, 58, 10500. 5, , , , , , , , , , Adv. Mater. 2022, 34, 2108400. 6, , , , , , , , , , , , , , , , Nat. Energy 2020, 5, 386. 7, , , , , , , , , , , , Nat.
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